WebSep 22, 2024 · The first water-soluble biphen [4]arene containing eight carboxylato moieties (carboxylatobiphen [4]arene, CBP4) has been synthesized. Selective molecular recognition of acetylcholine (ACh) against… 49 Syntheses of a pillar [4]arene [1]quinone and a difunctionalized pillar [5]arene by partial oxidation. WebMar 3, 2024 · Biphen[n]arenes would be a promising family of workhorses in supramolecular chemistry. In this Account, we summarize our recent work on the chemistry of biphen[ n …
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WebOct 19, 2016 · Biphen [ n ]arenes ( n =3, 4) are a new family of macrocyclic hosts. Here, we describe the molecular recognition behavior of hydroxylated biphen [4]arene (OHBP4) for the first time. WebDec 8, 2024 · Conformational exchanges of synthetic macrocyclic acceptors are rather fast, which is rarely studied in the absence of guests. Here, we report multiple stimuli-responsive conformational exchanges between two preexisting conformations of 2,2′,4,4′-tetramethoxyl biphen[3]arene (MeBP3) macrocycle. Structures of these two conformations are both … rayleigh leisure indoor bowls club
Multiple Stimuli-Responsive Conformational Exchanges …
WebTo design and exploit novel macrocyclic synthetic receptors is a permanent and challenging topic in supramolecular chemistry. Here we describe the one-pot synthesis, unique geometries and intriguing host–guest properties of a new class of supramolecular macrocycles – biphen[n]arenes (n = 3, 4), which are made up of 4,4′-biphenol or 4,4′ … WebAug 22, 2024 · Biphen [ n ]arenes, as a new generation of macrocycles, also have a unique topological structure. In this part, we will detailedly present the topological … WebMar 9, 2024 · There is no report about the unsubstituted point on the modified benzene ring, but new hosts of synthetic macrocyclic arenes closely related to pillar[n]arenes have emerged in Biphen[n]arenes, a new class of macrocyclic hosts closely related to pillarenes, were first designed and synthesized by Li and co-workers in 2015, and they are … rayleigh length calculation